Glossary of SMA
Shape memory alloys (SMAs) are metals that "remember" their original shapes. Shape memory alloys (SMA’s) are metals which exhibit two very unique properties, pseudo-elasticity and the shape memory effect. SMA’s are useful for such things as actuators which are materials that “change shape, stiffness, position, and other mechanical characteristics in response to temperature or electromagnetic fields”. The alloys that exhibit so-called “shape memory” can undergo surprisingly large amounts of strain and then, upon temperature increase or unloading, revert to their original shape. Ni-Ti based shape memory alloys have to date provided the best combination of materials properties for most commercial applications.
Af – Austenite Finish

The    temperature at which the Martensite to Austenite transformation is completed    in a single stage transformation.

As – Austenite Start

The    temperature at which the Martensite to Austenite transformation begins on    heating in a single stage transformation.

Activation Range

The    distance a spring can be stretched, or the angle a wire can be bent, without    permanent deformation; the useful, working range of a spring or wire.

Anneal

A heat    treat process designed to remove the effects of cold work and/or aging heat    treatments.

Austenite

The    high temperature phase of Nickel Titanium. In its austenitic phase, NiTi is    stiff and elastic and will immediately return to shape after bending. (See    Superelasticity.)  Austenitic NiTi wire    has the B2 body-centered cubic crystal structure.

BFR Test

The    Bend and Free Recovery test provides an analysis of bend angle to    temperature, and it can be used in determining As and Af temperatures of a    NiTi wire.

Compression Spring

Springs    which are manufactured with open spaces between helixes. Compression springs    are typically used in applications were they are compressed to provide a    “pushing” force.

DSC Analysis

Differential    Scanning Calorimetry – a laboratory procedure used to identify the thermally    induced transformations of a particular alloy.

Elasticity

The    apparent ease with which a wire can be deflected without incurring permanent    deformation.

Extension Spring

Springs    which are manufactured with closed coils, such that the helixes are wound    tightly together. Extension springs are typically used in tensile to provide    pulling forces.

Hysteresis

The    difference in bending loads during loading and unloading in a test such as 3    Point Bending.

Martensite

The    low temperature phase of Nickel Titanium. In its martensitic phase, Niti is    soft and bends easily. NiTi will stay in this state until exposed to heat    above its TTR. NiTi in its martensitic state is responsive to chilling, as it    becomes even softer and more easily bent. Martensitic NiTi has the B19    monoclinic crystal structure.

Md  – Martensite Desist

The    temperature above Af at which stress induced martensite will no longer form.    Typically =80°C above functional Af.

Mf - Martensitic Finish

The    temperature at which the transformation from Austenite to Martensite is    completed on cooling a single stage transformation.

Ms – Martensite Start

The    temperature at which the transformation from Austenite to Martensite begins    on cooling in a single stage transformation.

Permanent Deformation

Usually    in reference to the angle or percentage that a wire or component does not    return to its original shape after being strained.

Resiliency

A    material’s ability to resist permanent deformation when bent.

Shape Memory

An    apparent plastic deformation in the martensitic phase, which undergoes a    thermo-elastic change in the crystal structure when heated through its    transformation temperature range, resulting in a recovery of the deformation.    The ability for a preformed wire, below its TTR, to be deformed to some    degree and then, upon heating, to return to its original shape. Further    details are available on the Material    Characteristics page.

Stress Induced Martensite

The    spontaneous phase change of the crystal lattice from Austenite to Martensite    as stress is applied to the material at a temperature above Af. Stress    Induced Martensite spontaneously reverts to Austenite as stress is removed,    unless permanent deformation has been introduced into the material.

Superelasticity

A    nonlinear recoverable deformation behavior of Nickel Titanium shape memory    alloys at temperatures above Af. The nonlinear deformation arises from the    stress-induced formation of martensite on loading and the spontaneous    reversion of this crystal structure to austenite upon unloading. Further    details are available on the Material    Characteristics page.

Tensile Strength

When    stretched, the maximum force a wire can withstand without breaking.

Thermal

Term    used for martensitic wire, as it is responsive to heat-activation. See    Martensite.

Transformation Temperature Range (TTR)

For    shape memory alloys, such as Nickel Titanium, a change of phase occurs, such    as from martensite to austenite, in a specific temperature range. The TTR is    adjustable by several means to produce desired characteristics.

Shape Memory Alloys (SMA's) are novel materials which have the ability to return to a predetermined shape when heated. When an SMA is cold, or below its transformation temperature, it has a very low yield strength and can be deformed quite easily into any new shape--which it will retain. However, when the material is heated above its transformation temperature it undergoes a change in crystal structure which causes it to return to its original shape. If the SMA encounters any resistance during this transformation, it can generate extremely large forces. This phenomenon provides a unique mechanism for remote actuation. The most common shape memory material is an alloy of nickel and titanium called Nitinol. This particular alloy has very good electrical and mechanical properties, long fatigue life, and high corrosion resistance. Shape memory alloys, however, are not for all applications. One must take into account the forces, displacements, temperature conditions, and cycle rates required of a particular actuator.
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